E-Commerce Configuration Guide : Site Configuration Settings : Email Settings : MailBCC
 
MailBCC
Key value:
Any valid e-mail address or blank
Description:
Used to populate the BCC field of the confirmation e-mails from your site. If entering multiple e-mail addresses into this key, each e-mail address is separated with only a comma.
See also:
MailFromAddr
MailFromName
MailCC
MailSubject